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The performances of a vanadium redox flow battery with interdigitated flow field, hierarchical interdigitated flow field, and tapered hierarchical interdigitated flow field were evaluated through 3D numerical model.
Vanadium redox flow battery (VRFB) is an essential technology for realizing large-scale, long-term energy storage. Among its components, the flow field structure plays a crucial factor affecting the battery performance. So far, there still exists uneven electrolyte distribution leading to low efficiency.
Conclusions The stack is the core component of large-scale flow battery system. Based on the leakage circuit, mass and energy conservation, electrochemicals reaction in porous electrode, and also the effect of electric field on vanadium ion cross permeation in membrane, a model of kilowatt vanadium flow battery stack was established.
Author to whom correspondence should be addressed. In vanadium redox flow batteries, the flow field geometry plays a dramatic role on the distribution of the electrolyte and its design results from the trade-off between high battery performance and low pressure drops.
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With the increasing application of the lithium-ion battery, higher requirements are put forward for battery thermal management systems. Compared with other cooling methods, liquid cooling is an efficient cooling method, which can control the maximum temperature and maximum temperature difference of the battery within an acceptable range.
Liquid cooling, due to its high thermal conductivity, is widely used in battery thermal management systems. This paper first introduces thermal management of lithium-ion batteries and liquid-cooled BTMS.
The lithium-ion battery thermal management system proposed by Al-Zareer et al.119 employs boiling liquid propane to remove the heat generated by the battery, while propane vapor is used to cool parts of the battery not covered by liquid propane.
The media such as liquid, phase change material, metal and air play a significant role in battery cooling systems. [5, 18, 19] As the metal media, micro heat pipe array (MHPA) is commonly used in the lithium-ion battery cooling method due to the characteristics of compactness, and the MHPA can enhance the stability and safety of battery pack.
Among the numerous all-liquid flow batteries, all-liquid iron-based flow batteries with iron complexes redox couples serving as active material are appropriate for long duration energy storage because of the low cost of the iron electrolyte and the flexible design of power and capacity.
Other flow-type batteries include the zinc–cerium battery, the zinc–bromine battery, and the hydrogen–bromine battery. A membraneless battery relies on laminar flow in which two liquids are pumped through a channel, where they undergo electrochemical reactions to store or release energy. The solutions pass in parallel, with little mixing.
Whereas lithium-ion batteries can deliver big amounts of energy in a short period of time (1 to 2 hours), flow batteries have much less power density. That means they are better at delivering a consistent amount of less energy over a longer period of time (up to 10 hours).
Herein, we propose a low-cost alkaline all-iron flow battery by coupling ferri/ferro-cyanide redox couple with ferric/ferrous-gluconate complexes redox couple.
